粮油食品科技

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石墨烯吸附材料结构性质解析及其在菜籽油脱色中的应用
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Structural and Performance Analysis of Graphene Adsorption Materials and Their Application in Rapeseed Oil Decolorization
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    摘要:

    为了克服活性白土在油脂工业脱色中的操作温度高、残油率大、废白土处理困难等缺点,开发超强吸附材料石墨烯作为新型吸附剂用于油脂脱色。采用扫描电子显微镜、傅立叶红外光谱仪和显微共聚焦拉曼光谱仪等仪器对石墨烯纳米片(GNP)和氧化石墨烯(GO)的结构与表面性质分析进行了表征。在明确石墨烯材料结构特征的基础上,将其用于菜籽油的脱色,并探讨了石墨烯种类、添加量,反应压力、温度以及反应时间等因素对石墨烯在油脂体系脱色效果的影响。结果表明:与GO相比,GNP对菜籽油脱色效果更佳,并且在低温(45 ℃)条件下对油脂中叶绿素表现出独特吸附性能。单因素结果表明,在GNP添加量2.0%(wt)、温度45 ℃、吸附时间5 min的优化条件下,GNP可以脱除油中80.6%的叶绿素。GNP作吸附剂用于油脂脱色具有反应温度低、吸附时间短的优势,在油脂低温适度加工中具有潜在应用前景。

    Abstract:

    To overcome the shortcomings of activated bleaching clay in the decolorization of edible oil industry, such as high operating temperature, large residual oil ratio, and difficulty in the disposal of waste bleaching clay, this work developed the super-strong adsorbent material, graphene, as a new type of adsorbent for the decolorization of rapeseed oil. Graphene nanoplatelets (GNP) and graphene oxide (GO) were characterized by scanning electron microscope. Fourier infrared spectrometer and Raman spectrometer, etc After clarifying the structural characteristics of graphene, they were used for the decolorization of rapeseed oil, and the effects of graphene species, addition amount, pressure, temperature, and reaction time on the decolorization of rapeseed oil were investigated. The results showed that GNP was more effective in rapeseed oil decolorization compared with GO and exhibited unique adsorption properties for chlorophyll in oil at low temperature (45 ℃). The one-factor results showed that GNP could remove 80.6% of chlorophyll in oil under the optimized conditions of GNP addition of 2.0%, temperature of 45 ℃ and adsorption time of 5 min. GNP as adsorbent for oil decolorization has the advantages of low reaction temperature and short adsorption time, which could have the potential application prospects in low temperature moderate processing of oils and fats.

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李晓澄,吕亚萍,叶 展*.石墨烯吸附材料结构性质解析及其在菜籽油脱色中的应用[J].粮油食品科技,2024,32(4):105-111.

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  • 在线发布日期: 2024-07-23
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